4-Methoxy-N-(4-nitrobenzyl)aniline
نویسندگان
چکیده
In the title compound, C(14)H(14)N(2)O(3), the nitro group is nearly coplanar with the benzene ring to which it is bonded [dihedral angle = 1.70 (2)°], and this ring is para-substituted by the amino-methyl-ene group. The dihedral angle between the benzene rings is 57.8 (1)°. The crystal structure is stabilized by N-H⋯O and C-H⋯O hydrogen bonds and weak C-H⋯π inter-actions are also observed.
منابع مشابه
4-Methoxy-N-(2-nitrobenzylidene)aniline
The title compound, C(14)H(12)N(2)O(3), was prepared by reaction of 2-nitro-benzaldehyde with 4-methoxy-benzenamine at 377 K. The molecule has an E configuration, with a dihedral angle between the two benzene rings of 43.3 (5)°. An intermolecular C-H⋯O interaction links molecules in zigzag chains down the a axis.
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متن کامل2-(4-Methoxy-2-methylanilino)-1,2-diphenylethanone
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متن کاملCrystal structures of 4-methoxy-N-(4-methylphenyl)benzenesulfonamide and N-(4-fluorophenyl)-4-methoxybenzenesulfonamide
Crystal structures of two N-(ar-yl)aryl-sulfonamides, namely, 4-meth-oxy-N-(4-methyl-phen-yl)benzene-sulfonamide, C14H15NO3S, (I), and N-(4-fluoro-phen-yl)-4-meth-oxy-benzene-sulfonamide, C13H12FNO3S, (II), were determined and analyzed. In (I), the benzene-sulfonamide ring is disordered over two orientations, in a 0.516 (7):0.484 (7) ratio, which are inclined to each other at 28.0 (1)°. In (I),...
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012